The important role of Quinuclidin-3-yl acetate

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One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, Product Details of 827-61-2, such as the rate of change in the concentration of reactants or products with time.In a article, authors is Grob, Cyril A., mentioned the application of 827-61-2, Name is Quinuclidin-3-yl acetate, molecular formula is C9H15NO2

95. Inductive Charge Dispersal in Quinuclidinium Ions. Polar Effects, Part 13

Inductive charge dispersal to the alpha-, beta-, and gamma-positions of the solvated quinuclidinium ion has been examined by comparing the pKa and the derived inductivities rho1 of several 2-, 3- and 4-substituted quinuclidinium perchlorates 4, 5, and 6, respectively.The same inductivity is observed at the practically equidistant beta- and gamma-positions.It, therefore, appears that polar substituent effects are transmitted directly through the molecule.As expected, inductivity is considerably higher at the alpha-positions where through-bond and direct induction coincide.The fact that the pKa of all three series of salts correlate linearly with each other points to the common nature of these inductive electron displacements.

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Reference£º
Quinuclidine – Wikipedia,
Quinuclidine | C7H59N | ChemSpider