Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 36620-11-8, is researched, SMILESS is [F-][B+3]([F-])([F-])[F-].C12=C3[Rh+]14567(C8=C5C9C6=C7C8C9)C%10=C4C2CC3%10, Molecular C14H8BF4RhJournal, Organic Chemistry Frontiers called Porous organic polymers as heterogeneous ligands for highly selective hydroacylation, Author is Jiang, Ya-Nan; Li, Ding-Chang; Yang, Ying; Zhan, Zhuang-Ping, the main research direction is thiomethyl arylaldehyde alkyne rhodium catalyst hydroacylation; methylsulfanylarylpropenone preparation regioselective diastereoselective.Electric Literature of C14H8BF4Rh.
A porous organic polymer (POL-dppe) was synthesized and employed as a heterogeneous ligand for selective hydroacylation of alkynes. The polymer shows high linear selectivity and catalytic efficiency toward a broad range of alkynes and β-S substituted aldehydes. Owing to the confinement effect of the microporous structure, POL-dppe was far superior to the monomeric dppe ligand in controlling the selectivity of electron-deficient alkynes. The use of a porous organic polymer as a regioselective and efficient ligand in hydroacylation is reported for the first time.
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Reference:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider