Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 36620-11-8, is researched, Molecular C14H8BF4Rh, about How Cationic Metalloligands Affect the Coordination of Lewis Basic Ligands in RhI Complexes, the main research direction is pyridylphosphine rhodium cationic metalloligand Lewis basic preparation crystal structure; hydroformylation catalyst phosphinopyridine rhodium cationic complex preparation; crystal mol structure phosphinopyridine rhodium metalloligand zinc magnesium complex.Computed Properties of C14H8BF4Rh.
A series of RhI complexes featuring cationic diphosphinometal ligands (PMPn+) has been synthesized, and the effect of the dative RhI → Mn+ interactions on other ligands coordinated to the RhI center were studied. The Rh-CO bond strength in square pyramidal [(PMP)Rh(CO)X]n+-type complexes (X = Cl, H) is dominated by the charge of the metalloligand. Complex [(PZnP)Rh(CO)H](NTf2)2 (7) was evaluated for its competence in hydroformylation catalysis. Computational anal. of octahedral [(PMP)Rh(CO)2H]n+ model complexes revealed a strengthening of the Rh-CO bond trans to the metalloligand with increasing at. number of the metalloligand.
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Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider