The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Bis(norbornadiene)rhodium (I) tetrafluoroborate( cas:36620-11-8 ) is researched.Recommanded Product: Bis(norbornadiene)rhodium (I) tetrafluoroborate.Fernandez-Perez, Hector; Lenartowicz, Pawel; Carreras, Lucas; Grabulosa, Arnald; Kafarski, Pawel; Vidal-Ferran, Anton published the article 《Access to α-Aminophosphonic Acid Derivatives and Phosphonopeptides by [Rh(P-OP)]-Catalyzed Stereoselective Hydrogenation》 about this compound( cas:36620-11-8 ) in Journal of Organic Chemistry. Keywords: vinyl phosphonate rhodium catalyst hydrogenation mol structure; alpha aminophosphonic acid phophonopeptide asym preparation. Let’s learn more about this compound (cas:36620-11-8).
The hydrogenation of N-substituted vinylphosphonates using rhodium complexes derived from P-OP ligands L1, ent-L1 or (R,R)-Me-DuPHOS as catalysts has been successfully accomplished, achieving very high levels of stereoselectivity (up to 99% ee or de). The described synthetic strategy allowed for the efficient preparation of alpha-aminophosphonic acid derivatives, e.g. I, and phosphonopeptides, e.g. II, which are valuable building blocks for the preparation of biol. relevant mols.
Compound(36620-11-8)Recommanded Product: Bis(norbornadiene)rhodium (I) tetrafluoroborate received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(Bis(norbornadiene)rhodium (I) tetrafluoroborate), if you are interested, you can check out my other related articles.
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Quinuclidine – Wikipedia,
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