Continuously updated synthesis method about 36620-11-8

Here is just a brief introduction to this compound(36620-11-8)Safety of Bis(norbornadiene)rhodium (I) tetrafluoroborate, more information about the compound(Bis(norbornadiene)rhodium (I) tetrafluoroborate) is in the article, you can click the link below.

Safety of Bis(norbornadiene)rhodium (I) tetrafluoroborate. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Bis(norbornadiene)rhodium (I) tetrafluoroborate, is researched, Molecular C14H8BF4Rh, CAS is 36620-11-8, about Efficient Access to Chiral β-Borylated Carboxylic Esters via Rh-Catalyzed Hydrogenation. Author is Liu, Gang; Li, Anqi; Qin, Xueyuan; Han, Zhengyu; Dong, Xiu-Qin; Zhang, Xumu.

Rh/bisphosphine-thiourea ligand (ZhaoPhos)-catalyzed asym. hydrogenation of (Z)-β-substituted-β-boryl-α,β-unsaturated esters was successfully developed, furnishing a variety of chiral β-borylated carboxylic esters with high yields and excellent enantioselectivities (up to 99% yield and >99% ee). The gram-scale asym. hydrogenation was performed efficiently in the presence of only 0.05 mol% (S/C = 2000) catalyst loading with full conversion, 99% yield and 99% ee. Moreover, the hydrogenation product was easily converted to other versatile synthetic intermediates, such as Me (S)-3-hydroxy-3-phenylpropanoate and Me (S)-3-(furan-2-yl)-3-phenylpropanoate.

Here is just a brief introduction to this compound(36620-11-8)Safety of Bis(norbornadiene)rhodium (I) tetrafluoroborate, more information about the compound(Bis(norbornadiene)rhodium (I) tetrafluoroborate) is in the article, you can click the link below.

Reference:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider