Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 36620-11-8, is researched, Molecular C14H8BF4Rh, about Practical and efficient preparation of the chiral 4-bromotryptophan derivative by Rh-catalyzed hydrogenation, the main research direction is bromotryptophan enantioselective preparation rhodium catalyzed asym hydrogenation bromoindole.Product Details of 36620-11-8.
An efficient three-step sequence has been developed for the preparation of a chiral 4-bromotryptophan derivative starting from the com. available 4-bromoindole. Key to the synthesis was the generation of the chiral center via a Rh-catalyzed asym. hydrogenation of a dehydrotryptophan precursor with 95% yield and >99% ee. Notably, the whole synthetic route required no column chromatog. operations and was readily conducted on large scales.
There is still a lot of research devoted to this compound(SMILES：[F-][B+3]([F-])([F-])[F-].C12=C3[Rh+]14567(C8=C5C9C6=C7C8C9)C%10=C4C2CC3%10)Product Details of 36620-11-8, and with the development of science, more effects of this compound(36620-11-8) can be discovered.
Reference:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider