In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called How Cationic Metalloligands Affect the Coordination of Lewis Basic Ligands in RhI Complexes, published in 2021-12-13, which mentions a compound: 36620-11-8, mainly applied to pyridylphosphine rhodium cationic metalloligand Lewis basic preparation crystal structure; hydroformylation catalyst phosphinopyridine rhodium cationic complex preparation; crystal mol structure phosphinopyridine rhodium metalloligand zinc magnesium complex, Category: quinuclidine.
A series of RhI complexes featuring cationic diphosphinometal ligands (PMPn+) has been synthesized, and the effect of the dative RhI → Mn+ interactions on other ligands coordinated to the RhI center were studied. The Rh-CO bond strength in square pyramidal [(PMP)Rh(CO)X]n+-type complexes (X = Cl, H) is dominated by the charge of the metalloligand. Complex [(PZnP)Rh(CO)H](NTf2)2 (7) was evaluated for its competence in hydroformylation catalysis. Computational anal. of octahedral [(PMP)Rh(CO)2H]n+ model complexes revealed a strengthening of the Rh-CO bond trans to the metalloligand with increasing at. number of the metalloligand.
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Reference:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider