Sources of common compounds: 36620-11-8

As far as I know, this compound(36620-11-8)Formula: C14H8BF4Rh can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Functionalized pyrroles from vinylaziridines and alkynes via rhodium-catalyzed domino ring-opening cyclization followed by C=C bond migration, published in 2019-03-01, which mentions a compound: 36620-11-8, mainly applied to pyrrolepropanoate pyrrolepropanone preparation; rhodium catalyst cycloaddition aryl alkyne aziridinylpropenoate isomerization DABCO, Formula: C14H8BF4Rh.

In the presence of Rh(nbd)2BF4 (nbd = norbornadiene), an aziridinylpropenoate I underwent cycloaddition reactions with aryl alkynes such as RCCH (R = Ph, 4-MeC6H4, 4-MeOC6H4, 4-ClC6H4, 4-F3CC6H4, 4-MeCOC6H4, 4-EtO2CC6H4, 2,4,6-Me3C6H2, 1-naphthyl) followed by isomerization of the intermediates with DABCO to yield arylpyrrolepropanoates such as II (R = Ph, 4-MeC6H4, 4-MeOC6H4, 4-ClC6H4, 4-F3CC6H4, 4-MeCOC6H4, 4-EtO2CC6H4, 2,4,6-Me3C6H2, 1-naphthyl). An aziridinylpropenone underwent analogous cycloaddition and isomerization reactions with phenylacetylene to yield a phenylpyrrolylpropanone.

As far as I know, this compound(36620-11-8)Formula: C14H8BF4Rh can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.

Reference:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider