In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called A Gallium-based Chiral Solvating Agent Enables the Use of 1H NMR Spectroscopy to Differentiate Chiral Alcohols, published in 2019-09-27, which mentions a compound: 36620-11-8, mainly applied to gallium differentiate alc NMR spectroscopy; Analytical Chemistry; Chemistry; Chirality in Analytical Chemistry; Stereochemistry, SDS of cas: 36620-11-8.
In situ, direct 1H NMR chiral anal. by using chiral solvating agents is a convenient and efficient anal. technique. Here we developed a Ga-based chiral anionic metal complex for 1H NMR chiral anal. of alcs. Utilizing the optimal pKa value, the Ga complex was able to differentiate 1H NMR signals of each (R)- and (S)-enantiomer of alcs., measured at room temperature This direct 1H NMR chiral anal. of alcs. was used to rapidly determine enantiomeric excess and conversion in a kinetic resolution and an asym. synthesis.
As far as I know, this compound(36620-11-8)SDS of cas: 36620-11-8 can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.
Reference:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider