Extracurricular laboratory: Synthetic route of 36620-11-8

When you point to this article, it is believed that you are also very interested in this compound(36620-11-8)Application In Synthesis of Bis(norbornadiene)rhodium (I) tetrafluoroborate and due to space limitations, I can only present the most important information.

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Catalytic asymmetric hydrogenation of (Z)-α-dehydroamido boronate esters: direct route to alkyl-substituted α-amidoboronic esters, published in 2020, which mentions a compound: 36620-11-8, Name is Bis(norbornadiene)rhodium (I) tetrafluoroborate, Molecular C14H8BF4Rh, Application In Synthesis of Bis(norbornadiene)rhodium (I) tetrafluoroborate.

The direct catalytic asym. hydrogenation of (Z)-α-dehydroamino boronate esters was realized. Using this approach, a class of therapeutically relevant alkyl-substituted α-amidoboronic esters was easily synthesized in high yields with generally excellent enantioselectivities (up to 99% yield and 99% ee). The utility of the products has been demonstrated by transformation to their corresponding boronic acid derivatives by a Pd-catalyzed borylation reaction and an efficient synthesis of a potential intermediate of bortezomib. The clean, atom-economic and environment friendly nature of this catalytic asym. hydrogenation process would make this approach a new alternative for the production of alkyl-substituted α-amidoboronic esters of great potential in the area of organic synthesis and medicinal chem.

When you point to this article, it is believed that you are also very interested in this compound(36620-11-8)Application In Synthesis of Bis(norbornadiene)rhodium (I) tetrafluoroborate and due to space limitations, I can only present the most important information.

Reference:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider