The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Bis(norbornadiene)rhodium (I) tetrafluoroborate, is researched, Molecular C14H8BF4Rh, CAS is 36620-11-8, about Enantioselective Hydrogenation of Endocyclic Enones: the Solution to a Historical Problem, the main research direction is cyclopentenone rhodium catalyst enantioselective chemoselective hydrogenation; cyclopentanone preparation.Category: quinuclidine.
Herein, an efficient method to reduce endocyclic enones with mol. hydrogen was reported. Catalyzed by a rhodium/Zhaophos complex, a variety of enones with five-, six- or seven-member ring were hydrogenated with high enantioselectivity (92%-99% ee). Excellent chemo- and enantioselectivity demonstrated this method was successfully applied in the enantioselective hydrogenation of citral to produce enantio-enriched citronellal.
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Quinuclidine | C7H13N | ChemSpider