Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 36620-11-8, is researched, SMILESS is [F-][B+3]([F-])([F-])[F-].C12=C3[Rh+]14567(C8=C5C9C6=C7C8C9)C%10=C4C2CC3%10, Molecular C14H8BF4RhJournal, Article, Research Support, Non-U.S. Gov’t, Journal of the American Chemical Society called Development of Robust Heterogeneous Chiral Rhodium Catalysts Utilizing Acid-Base and Electrostatic Interactions for Efficient Continuous-Flow Asymmetric Hydrogenations, Author is Saito, Yuki; Kobayashi, Shu, the main research direction is amide preparation continuous flow asym hydrogenation enamide dehydroamino acid; heterogeneous chiral rhodium catalyst acid base electrostatic interaction.Application of 36620-11-8.
Heterogeneous chiral Rh catalysts based on acid-base and electrostatic interactions have been developed. The robust catalysts demonstrate high activity and selectivity in the continuous-flow asym. hydrogenation of a wide variety of enamides and dehydroamino acids, providing optically active amides without leaching of metal species. The chiral environments can be easily tuned by changing the chiral ligands, demonstrating the high versatility of the heterogeneous catalysts. By applying these efficient catalysts, continuous synthesis of several active pharmaceutical ingredient intermediates was achieved.
Compounds in my other articles are similar to this one(Bis(norbornadiene)rhodium (I) tetrafluoroborate)Application of 36620-11-8, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.
Reference:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider