Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Research Support, N.I.H., Extramural, Research Support, Non-U.S. Gov’t, Journal of the American Chemical Society called Rhodium-Catalyzed Asymmetric Hydroamination of Allyl Amines, Author is Vanable, Evan P.; Kennemur, Jennifer L.; Joyce, Leo A.; Ruck, Rebecca T.; Schultz, Danielle M.; Hull, Kami L., which mentions a compound: 36620-11-8, SMILESS is [F-][B+3]([F-])([F-])[F-].C12=C3[Rh+]14567(C8=C5C9C6=C7C8C9)C%10=C4C2CC3%10, Molecular C14H8BF4Rh, SDS of cas: 36620-11-8.
A Rh-catalyzed enantioselective hydroamination of allylamines using a chiral BIPHEP-type ligand is reported. Enantioenriched 1,2-diamines are formed in good yields and with excellent enantioselectivities. A diverse array of nucleophiles and amine directing groups are demonstrated, including deprotectable motifs. Finally, the methodol. was demonstrated toward the rapid synthesis of 2-methyl-moclobemide.
After consulting a lot of data, we found that this compound(36620-11-8)SDS of cas: 36620-11-8 can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider