The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Bis(norbornadiene)rhodium (I) tetrafluoroborate(SMILESS: [F-][B+3]([F-])([F-])[F-].C12=C3[Rh+]14567(C8=C5C9C6=C7C8C9)C%10=C4C2CC3%10,cas:36620-11-8) is researched.Electric Literature of C14H8BF4Rh. The article 《Porous organic polymers as heterogeneous ligands for highly selective hydroacylation》 in relation to this compound, is published in Organic Chemistry Frontiers. Let’s take a look at the latest research on this compound (cas:36620-11-8).
A porous organic polymer (POL-dppe) was synthesized and employed as a heterogeneous ligand for selective hydroacylation of alkynes. The polymer shows high linear selectivity and catalytic efficiency toward a broad range of alkynes and β-S substituted aldehydes. Owing to the confinement effect of the microporous structure, POL-dppe was far superior to the monomeric dppe ligand in controlling the selectivity of electron-deficient alkynes. The use of a porous organic polymer as a regioselective and efficient ligand in hydroacylation is reported for the first time.
The article 《Porous organic polymers as heterogeneous ligands for highly selective hydroacylation》 also mentions many details about this compound(36620-11-8)Quality Control of Bis(norbornadiene)rhodium (I) tetrafluoroborate, you can pay attention to it, because details determine success or failure
Reference:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider