Extended knowledge of 36620-11-8

Different reactions of this compound(Bis(norbornadiene)rhodium (I) tetrafluoroborate)Formula: C14H8BF4Rh require different conditions, so the reaction conditions are very important.

Formula: C14H8BF4Rh. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Bis(norbornadiene)rhodium (I) tetrafluoroborate, is researched, Molecular C14H8BF4Rh, CAS is 36620-11-8, about (Z)-Selective Hydroboration of Terminal Alkynes Catalyzed by a PSP-Pincer Rhodium Complex. Author is Lyu, Yanzong; Toriumi, Naoyuki; Iwasawa, Nobuharu.

A highly (Z)-selective hydroboration of terminal alkynes was achieved using a thioxanthene-based PSP-pincer Rh catalyst. This hydroboration exhibited good chemoselectivity toward alkynes over carbonyl compounds such as ketones and aldehydes. The mechanistic studies indicated the involvement of Rh-vinylidene intermediates, and the high (Z)-selectivity could be attributed to the rigid and electron-rich nature of the PSP-Rh catalyst.

Different reactions of this compound(Bis(norbornadiene)rhodium (I) tetrafluoroborate)Formula: C14H8BF4Rh require different conditions, so the reaction conditions are very important.

Reference:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider