The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Bis(norbornadiene)rhodium (I) tetrafluoroborate(SMILESS: [F-][B+3]([F-])([F-])[F-].C12=C3[Rh+]14567(C8=C5C9C6=C7C8C9)C%10=C4C2CC3%10,cas:36620-11-8) is researched.Formula: C14H8BF4Rh. The article 《Sequential Catalytic Functionalization of Aryltriazenyl Aldehydes for the Synthesis of Complex Benzenes》 in relation to this compound, is published in ACS Catalysis. Let’s take a look at the latest research on this compound (cas:36620-11-8).
We demonstrate that aryltriazenes can promote three distinctive types of C-H functionalization reactions, allowing the preparation of complex benzene mols. with diverse substitution patterns. 2-Triazenylbenzaldehydes are shown to be efficient substrates for Rh(I)-catalyzed intermol. alkyne hydroacylation reactions. The resulting triazene-substituted ketone products can then undergo either a Rh(III)-catalyzed C-H activation, or an electrophilic aromatic substitution reaction, achieving multifunctionalization of the benzene core. Subsequent triazene derivatization provides traceless products.
Different reactions of this compound(Bis(norbornadiene)rhodium (I) tetrafluoroborate)COA of Formula: C14H8BF4Rh require different conditions, so the reaction conditions are very important.
Reference:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider