Fernandez-Perez, Hector; Lenartowicz, Pawel; Carreras, Lucas; Grabulosa, Arnald; Kafarski, Pawel; Vidal-Ferran, Anton published the article 《Access to α-Aminophosphonic Acid Derivatives and Phosphonopeptides by [Rh(P-OP)]-Catalyzed Stereoselective Hydrogenation》. Keywords: vinyl phosphonate rhodium catalyst hydrogenation mol structure; alpha aminophosphonic acid phophonopeptide asym preparation.They researched the compound: Bis(norbornadiene)rhodium (I) tetrafluoroborate( cas:36620-11-8 ).Application of 36620-11-8. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:36620-11-8) here.
The hydrogenation of N-substituted vinylphosphonates using rhodium complexes derived from P-OP ligands L1, ent-L1 or (R,R)-Me-DuPHOS as catalysts has been successfully accomplished, achieving very high levels of stereoselectivity (up to 99% ee or de). The described synthetic strategy allowed for the efficient preparation of alpha-aminophosphonic acid derivatives, e.g. I, and phosphonopeptides, e.g. II, which are valuable building blocks for the preparation of biol. relevant mols.
The article 《Access to α-Aminophosphonic Acid Derivatives and Phosphonopeptides by [Rh(P-OP)]-Catalyzed Stereoselective Hydrogenation》 also mentions many details about this compound(36620-11-8)Application of 36620-11-8, you can pay attention to it, because details determine success or failure
Reference:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider