Shabarov, Yu. S.’s team published research in Zhurnal Organicheskoi Khimii in 4 | CAS: 20029-52-1

Zhurnal Organicheskoi Khimii published new progress about 20029-52-1. 20029-52-1 belongs to quinuclidine, auxiliary class Carboxylic acid,Benzene, name is 4-Cyclohexylbenzoic acid, and the molecular formula is C9H4F6O, Name: 4-Cyclohexylbenzoic acid.

Shabarov, Yu. S. published the artcileCyclopropanes and cyclobutanes. LVIII. p-Bicyclo[n.1.0]alk-1-ylbenzoic acids and -anilines, Name: 4-Cyclohexylbenzoic acid, the publication is Zhurnal Organicheskoi Khimii (1968), 4(7), 1175-80, database is CAplus.

The oxidation of p-RC6H4COMe (I) with NaOBr gave p-RC6H4CO2H (II). The reaction of II with SOCl2 gave the corresponding acid chlorides which were treated with NH4OH to give p-RC6H4CONH2. The action of NaOBr on the amides gave p-RC6H4NH2 (III). The alternative preparation of III involved converting I to p-RC6H4C(:NOH)Me, which with PCl5 were rearranged to p-RC6H4NHAc (IV). Saponification of IV gave III. Most III were converted to p-RC6H4NHC(:S)NHPh (by treating with PhN:C:S) for the identification purposes. The II and III prepared were (R in II and III given): cyclohexyl, cyclopentyl, bicyclo[3.1.0]hex-1-yl, and bicyclo[4.1.0]hept-1-yl. Their pK values and Hammett constant were determined

Zhurnal Organicheskoi Khimii published new progress about 20029-52-1. 20029-52-1 belongs to quinuclidine, auxiliary class Carboxylic acid,Benzene, name is 4-Cyclohexylbenzoic acid, and the molecular formula is C9H4F6O, Name: 4-Cyclohexylbenzoic acid.

Referemce:
https://en.wikipedia.org/wiki/Quinuclidine,
Quinuclidine | C7H13N | ChemSpider