Sun, Yong-Hui published the artcileA diversity-oriented synthesis of bioactive benzanilides via a regioselective C(sp2)-H hydroxylation strategy, SDS of cas: 20029-52-1, the publication is Chemical Science (2016), 7(3), 2229-2238, database is CAplus and MEDLINE.
Hydroxylated benzanilides such as I (R1 = H, 4-Me, 3-F, etc.; R2 = H, 4-Me, 3-F, etc.; R3 = Me, Et, Bn) were prepared by chemo- and regioselective C(sp2)-H hydroxylation using palladium and ruthenium catalysts. Ruthenium catalysts yielded N-aryl hydroxybenzamides, while palladium catalysts yielded N-hydroxyaryl benzamides. Computational investigations reveals that the regioselectivity is controlled mainly by both steric and electronic factors. Steric effects determine the regioselective outcomes in the Ru-catalyzed reaction, while electronic effects are dominant in the Pd-catalyzed reaction.
Chemical Science published new progress about 20029-52-1. 20029-52-1 belongs to quinuclidine, auxiliary class Carboxylic acid,Benzene, name is 4-Cyclohexylbenzoic acid, and the molecular formula is C48H47FeP, SDS of cas: 20029-52-1.
Referemce:
https://en.wikipedia.org/wiki/Quinuclidine,
Quinuclidine | C7H13N | ChemSpider