Novikov, I. N. published the artcileAutoxidation of p-dtcyclohexylbenzene, Formula: C13H16O2, the publication is Doklady Akademii Nauk SSSR (1963), 853-5, database is CAplus.
p-(C6H11)2C6H4 is easily oxidized by O in the presence of Mn rosinate with or without the presence of a bases [Na2CO3, NaOH, (NH4)2CO3]. The maximum concentration of hydroperoxide (56%) was accumulated at 110° in the presence of 6 mg. Mn rosinate/mole of the substrate, along with 2 g./mole Na2CO3. Temperatures above 110° tended to give lower yields of the hydroperoxide. The optimum yield was attained at 66% conversion. Higher temperatures gave more rapid consumption of O but lower yields of the hydroperoxide. The latter decomposed vigorously above 150°. Kinetic curves for typical runs are shown. Treatment of the reaction mixture with EtOH and cooling gave the recovered substrate, while the filtrate after being concentrated and treated with petr. ether gave p-C6H4[C6H11– OOH]2, m. 131-2° (with H2SO4 this gave hydroquinone), while the filtrate gave a monohydroperoxide, m. 85-6°, which in the presence of H2SO4 in AcOH at 50-60° gave 75% p-cyclohexylphenol and cyclohexanone. The residues after the separation of hydroperoxides also gave some p-C6H11C6H4CO2H, m. 190-1° (Me ester m. 44-5°).
Doklady Akademii Nauk SSSR published new progress about 20029-52-1. 20029-52-1 belongs to quinuclidine, auxiliary class Carboxylic acid,Benzene, name is 4-Cyclohexylbenzoic acid, and the molecular formula is C13H16O2, Formula: C13H16O2.
Referemce:
https://en.wikipedia.org/wiki/Quinuclidine,
Quinuclidine | C7H13N | ChemSpider