(1S,2S,4S,5R)-2-((R)-(Allyloxy)(quinolin-4-yl)methyl)-1-(anthracen-9-ylmethyl)-5-vinylquinuclidin-1-ium bromide (cas: 200132-54-3) belongs to quinuclidine derivatives. Quinuclidine is found as a structural component of some biomolecules including quinine. The reactions of quinuclidine compounds that lead to opening of the 1-azabi-cyclic system at the N-C and C-C bonds to give piperidine derivatives or, via subsequent rearrangements, derivatives of other heterocyclic systems, are correlated.Formula: C37H37BrN2O
Nucleophilic enantioselective synthesis of 6-fluoro-L-dopa via chiral catalytic phase-transfer alkylation was written by Tang, Ganghua;Tang, Xiaolan;Zhang, Lan;Wang, Yongxian. And the article was included in Zhongguo Yaowu Huaxue Zazhi in 2002.Formula: C37H37BrN2O This article mentions the following:
6-Fluoro-L-dopa was synthesized from 6-nitropiperonal via nucleophilic fluorination, reductive iodination, chiral catalytic phase-transfer alkylation, and hydrolysis reactions. The enantiomeric purity of 6-fluoro-L-dopa was determined by HPLC method using a chiral mobile phase and reversed-phase C18 column. The overall yield from 6-nitropiperonal was 38%, and enantiomeric purity of 6-fluoro-L-dopa was above 95%. In the experiment, the researchers used many compounds, for example, (1S,2S,4S,5R)-2-((R)-(Allyloxy)(quinolin-4-yl)methyl)-1-(anthracen-9-ylmethyl)-5-vinylquinuclidin-1-ium bromide (cas: 200132-54-3Formula: C37H37BrN2O).
(1S,2S,4S,5R)-2-((R)-(Allyloxy)(quinolin-4-yl)methyl)-1-(anthracen-9-ylmethyl)-5-vinylquinuclidin-1-ium bromide (cas: 200132-54-3) belongs to quinuclidine derivatives. Quinuclidine is found as a structural component of some biomolecules including quinine. The reactions of quinuclidine compounds that lead to opening of the 1-azabi-cyclic system at the N-C and C-C bonds to give piperidine derivatives or, via subsequent rearrangements, derivatives of other heterocyclic systems, are correlated.Formula: C37H37BrN2O
Referemce:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider