The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Bis(norbornadiene)rhodium (I) tetrafluoroborate( cas:36620-11-8 ) is researched.COA of Formula: C14H8BF4Rh.Gilbert, Sophie H.; Fuentes, Jose A.; Cordes, David B.; Slawin, Alexandra M. Z.; Clarke, Matthew L. published the article 《Phospholane-Phosphite Ligands for Rh Catalyzed Enantioselective Conjugate Addition: Unusually Reactive Catalysts for Challenging Couplings》 about this compound( cas:36620-11-8 ) in European Journal of Organic Chemistry. Keywords: phospholane phosphite chiral ligand preparation; rhodium catalyst enantioselective conjugate addition unsaturated carbonyl arylboronic acid. Let’s learn more about this compound (cas:36620-11-8).
The use of Rh catalysts derived from a phospholane-phosphite ligand were found to be more productive than the classic rhodium/BINAP system in enantioselective conjugate additions These catalysts enable the use of lower amounts of aryl boronic acid in an asym. arylation reaction that required an impractical excess of nucleophile. This catalyst was also found to enable the coupling of a poorly reactive Michael acceptor, N-CBz-2-3-dehydro-4-piperidone, or the coupling of poorly reactive 2-furyl boronic acids at ambient or near temperatures
Compound(36620-11-8)COA of Formula: C14H8BF4Rh received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(Bis(norbornadiene)rhodium (I) tetrafluoroborate), if you are interested, you can check out my other related articles.
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