Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 36620-11-8, is researched, SMILESS is [F-][B+3]([F-])([F-])[F-].C12=C3[Rh+]14567(C8=C5C9C6=C7C8C9)C%10=C4C2CC3%10, Molecular C14H8BF4RhJournal, Article, Research Support, U.S. Gov’t, Non-P.H.S., Research Support, Non-U.S. Gov’t, Organic Letters called Asymmetric total synthesis of C9′-epi-sinefungin, Author is Decultot, Ludovic; Policarpo, Rocco L.; Wright, Brandon A.; Huang, Danny; Shair, Matthew D., the main research direction is epi sinefungin modular scalable asym synthesis crystal structure.Quality Control of Bis(norbornadiene)rhodium (I) tetrafluoroborate.
The natural nucleoside (+)-sinefungin, structurally similar to cofactor S-adenosyl-L-methionine (SAM), inhibits various SAM-dependent methyltransferases (MTs). Access to sinefungin analogs could serve as the basis for the rational design of small-mol. methyltransferase inhibitors. We developed a route to the unnatural C9′ epimer of sinefungin that employed a diastereoselective Overman rearrangement to install the key C6′ amino stereo-center. The ability for late stage modification is highlighted, opening an avenue for the discovery of new MTs inhibitors.
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Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider