Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 36620-11-8, is researched, SMILESS is [F-][B+3]([F-])([F-])[F-].C12=C3[Rh+]14567(C8=C5C9C6=C7C8C9)C%10=C4C2CC3%10, Molecular C14H8BF4RhJournal, Article, Research Support, Non-U.S. Gov’t, Organic & Biomolecular Chemistry called Rh(I)-Catalyzed enantioselective and scalable [4 + 2] cycloaddition of 1,3-dienes with dialkyl acetylenedicarboxylates, Author is Bao, Robert Li-Yuan; Yin, Junjie; Shi, Lei; Zheng, Limin, the main research direction is rhodium phosphoramidite catalyzed enantioselective cycloaddition diene acetylenedicarboxylate; cyclohexadiene carbonyl derivative enantioselective synthesis.Recommanded Product: 36620-11-8.
An asym. intermol. [4 + 2] cycloaddition of 1,3-dienes with dialkyl acetylenedicarboxylates, which was catalyzed by a rhodium(I)-chiral phosphoramidite complex, was developed. This protocol provided a highly enantioselective access to prepare carbonyl substituted cyclohexa-1,4-dienes with up to 96% yield and >99% ee [e.g., di-Me acetylenedicarboxylate + (E)-1,3-nonadiene → I (96%, 99% ee)]. Notably, a cycloaddition on the 10 g scale gave the product in 92% yield and with 99% ee, which showed great potential for the scale-up synthesis of carbonyl substituted cyclohexa-1,4-dienes. In addition, oxidative aromatizations and hydrolysis of the products were also investigated.
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Reference:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider