Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 36620-11-8, is researched, SMILESS is [F-][B+3]([F-])([F-])[F-].C12=C3[Rh+]14567(C8=C5C9C6=C7C8C9)C%10=C4C2CC3%10, Molecular C14H8BF4RhJournal, Journal of Catalysis called HMF and furfural: Promising platform molecules in rhodium-catalyzed carbonylation reactions for the synthesis of furfuryl esters and tertiary amides, Author is Qi, Xinxin; Zhou, Rong; Ai, Han-Jun; Wu, Xiao-Feng, the main research direction is alkyl aryl iodide biomass rhodium carbonylation catalyst; furfuryl ester tertiary amide.COA of Formula: C14H8BF4Rh.
A biomass involved rhodium-catalyzed carbonylative synthesis of furfuryl esters and tertiary amides has been developed. 5-Hydroxymethylfurfural (HMF) was used as both substrate and CO surrogate for the first time in a carbonylation reaction, and both alkyl and aryl iodides were tolerated well to afford the desired furfuryl esters in moderate to good yields. In addition, furfural was also utilized as a CO source for the synthesis of tertiary amides. A variety of tertiary amides were obtained in moderate to excellent yields with good functional groups compatibility. Notably, tertiary amines were used as the amine source through a C-N bond cleavage pathway in the absence of addnl. oxidant.
The article 《HMF and furfural: Promising platform molecules in rhodium-catalyzed carbonylation reactions for the synthesis of furfuryl esters and tertiary amides》 also mentions many details about this compound(36620-11-8)COA of Formula: C14H8BF4Rh, you can pay attention to it, because details determine success or failure
Reference:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider