Reinheimer, John D.’s team published research in Ohio Journal of Science in 57 | CAS: 20029-52-1

Ohio Journal of Science published new progress about 20029-52-1. 20029-52-1 belongs to quinuclidine, auxiliary class Carboxylic acid,Benzene, name is 4-Cyclohexylbenzoic acid, and the molecular formula is C13H16O2, Application of 4-Cyclohexylbenzoic acid.

Reinheimer, John D. published the artcileThe oxidation of β-aroylpropionic acids by sodium hypochlorite, Application of 4-Cyclohexylbenzoic acid, the publication is Ohio Journal of Science (1957), 26-8, database is CAplus.

The title acids and their oxidation products are good detection derivatives for the hydrocarbons and the acids themselves. For sec-butylbenzene, ethylbenzene, mesitylene, butylbenzene, m-xylene, benzene, propylbenzene, Tetralin, tert-butylbenzene, toluene, o-xylene, phenylcyclohexane, cumene, β-methylnaphthalene, naphthalene, biphenyl, acenaphthene, and fluorene, the m.ps. of the aroylpropionic acid derivatives are, resp., 95.5-6.5°, 107.5-8.5°, 109-9.5°, 111-13.5°, 112-13°, 116.5-17.5°, 120.5-2.5°, 121-2°, 123.5-25°, 127.5-8.5°, 130-1°, 136-6.5°, 139.5-41.5°, 165-6°, 172-3°, 187.5-88°, 209-10°, and 212-13°, and the m.ps. of the corresponding oxidation products are, resp., 92.5-3.5°, 111-12°, 148-50°, 101-2°, 125.1-6.6°, 121.7°, 141.4-1.9°, 152.2-53°, 164.1-5.2°, 180.5-81°, 165.4-5.9°, 191.5-3.5°, 116.6-18°, 228.5-30.5°, 182-3°, 223.5-4.5°, 217-17.5°, and above 250° (sublimes). The oxidizing solution was prepared by dissolving 2 g. NaOH in 40 ml. 5.25% NaOCl and diluting to 100 ml.; 1 g. of aroylpropionic acid was dissolved therein and warmed on a water bath for 20-30 min., refluxed 0.5 hr., filtered, cooled, and precipitated with SO2. The water-washed derivative was recrystallized from ethanol or ethanol-water; yields for the various oxidation derivatives ranged from 52 to 97%.

Ohio Journal of Science published new progress about 20029-52-1. 20029-52-1 belongs to quinuclidine, auxiliary class Carboxylic acid,Benzene, name is 4-Cyclohexylbenzoic acid, and the molecular formula is C13H16O2, Application of 4-Cyclohexylbenzoic acid.

Referemce:
https://en.wikipedia.org/wiki/Quinuclidine,
Quinuclidine | C7H13N | ChemSpider